The Lower Silurian Longmaxi Formation in the south of Sichuan is a key player in the exploration and development of shale gas in China. Due to a highly complex topographic area, electromagnetic methods (EM) become important exploration means in this area. Many studies have been conducted on the shale mineral composition and electrical properties of shale, however, the correlation between sedimentary environments and the electrical properties of shale remain poorly understood. The electrical properties and sedimentary environment of the organic-rich shale of the Longmaxi Formation have been studied by means of X-ray diffraction, organic geochemistry, scanning electron microscopy and complex resistivity measurements. The discovered high quartz content of the Longmaxi Formation shale results in low resistivity. Deep-water shelf biogenic quartz contributes lower resistivity more than that of shallow-water terrigenous quartz. The deep-water anoxic and organic sedimentary environment led to major enrichment of pyrite, leading to a high polarization effect in shale. We present the correlation between the lithofacies types and electrical properties of Longmaxi Formation. The mixed siliceous shale lithofacies is the most favorable among the three lithofacies, which is characterized by high total organic carbon (TOC) content, high brittleness mineral content, high polarization and low resistivity (“three high and one low”). This feature is an effective identification of shale gas reservoirs by electromagnetic prospecting. Our study can provide constraints on electrical parameters of rocks for electromagnetic “sweet spot” exploration of shale gas, and so this has important geological significance to shale gas exploration and development. 相似文献
ABSTRACT This paper presents geochronological, geochemical, and zircon Hf–O isotope data for late Mesozoic intrusive rocks from the northeastern North China Craton (NCC), with the aim of constraining the late Mesozoic tectonic nature of the NE Asian continental margin. U–Pb zircon data indicate that the Late Mesozoic magmatism in the northeastern NCC can be subdivided into two stages: Late Jurassic (161 ? 156 Ma) and Early Cretaceous (125 ? 120 Ma). Late Jurassic magmatism consists mainly of monzogranites. These monzogranites display high Sr/Y ratios and the tetrad effect in their REE, respectively, and have negative εHf(t) values (?22.6 to ?15.8). The former indicates that the primary magma was generated by partial melting of thickened NCC lower crust, the latter suggests that the monzogranites were crystallized from highly fractionated magma, with the primary magma derived from partial melting of lower continental crust. Combined with the spatial distribution and rock associations of the Late Jurassic granitoids, we conclude that the Late Jurassic magmatism in the eastern NCC formed in a compressional environment related to oblique subduction of the Paleo-Pacific Plate beneath the Eurasia. The Early Cretaceous magmatism consists mainly of granitoids and quartz diorites. The quartz diorites formed by mixing of melts derived from the mantle and lower crust. The coeval granitoids are classified as high-K calc-alkaline and metaluminous to weakly peraluminous series. Some of the granitoids are similar to A-type granites. The granitoid εHf(t) values and TDM2 range from ?14.3 to ?1.4 and 2089 to 1274 Ma, respectively. These values indicate that their primary magma was derived from partial melting of lower crustal material of the NCC, but with a contribution of mantle-derived material. We therefore conclude that Early Cretaceous magmatism in the northeastern NCC occurred in an extensional environment related to westward subduction of the Paleo-Pacific Plate beneath Eurasia. 相似文献
Shale is observed to have strong anisotropy due to its unique mineralogy and microstructure, and this anisotropy property has significant impact on seismic and well-log data. The organic-rich marine shale in the southern and eastern Sichuan Basin is one of the most important shale-gas reservoir formations in China. To investigate the elastic anisotropy of this shale and its influencing factors, we performed ultrasonic velocity measurements, X-ray diffraction analysis, rock-eval pyrolysis and vitrinite reflectance measurement on the samples from the Upper Ordovician Wufeng Formation and the Lower Silurian Longmaxi Formation. The experimental results show the that:(1) the velocity anisotropy of the Wufeng-Longmaxi(WL) shale varies from 10% to 50%, and most samples have strong anisotropy;(2) the P-and S-wave anisotropy parameters(Thomsen's εand γ) increase with clay contents, but this relationship can be greatly affected by the clay orientation index;(3) organic matter content(OMC) is found to have little influence in seismic anisotropy for the over mature WL shale, whereas the OMC determines the magnitude of anisotropy of immature/mature shales(e.g. the Bakken shale or the Bazhenov shale) according to the published literatures, because organic matters in shales of different maturity have different morphologies and distributions;(4) the OMC of WL shale has positive correlation with quartz content, and this weakens the correlation between OMC and the magnitude of anisotropy to a certain extent. The results of this study provide an important rock-physics basis and data support for seismic anisotropy exploration, quantitative interpretation and resource evaluation of the organic-rich marine shales in southern China. 相似文献
In many arid ecosystems, vegetation frequently occurs in high-cover patches interspersed in a matrix of low plant cover. However, theoretical explanations for shrub patch pattern dynamics along climate gradients remain unclear on a large scale. This context aimed to assess the variance of the Reaumuria soongorica patch structure along the precipitation gradient and the factors that affect patch structure formation in the middle and lower Heihe River Basin (HRB). Field investigations on vegetation patterns and heterogeneity in soil properties were conducted during 2014 and 2015. The results showed that patch height, size and plant-to-patch distance were smaller in high precipitation habitats than in low precipitation sites. Climate, soil and vegetation explained 82.5% of the variance in patch structure. Spatially, R. soongorica shifted from a clumped to a random pattern on the landscape towards the MAP gradient, and heterogeneity in the surface soil properties (the ratio of biological soil crust (BSC) to bare gravels (BG)) determined the R. soongorica population distribution pattern in the middle and lower HRB. A conceptual model, which integrated water availability and plant facilitation and competition effects, was revealed that R. soongorica changed from a flexible water use strategy in high precipitation regions to a consistent water use strategy in low precipitation areas. Our study provides a comprehensive quantification of the variance in shrub patch structure along a precipitation gradient and may improve our understanding of vegetation pattern dynamics in the Gobi Desert under future climate change.
Due to the polarization effects of the Earth's surface reflection and atmospheric particles' scattering, high-precision retrieval of atmospheric parameters from near-infrared satellite data requires accurate vector atmospheric radiative transfer simulations. This paper presents a near-infrared vector radiative transfer model based on the doubling and adding method. This new model utilizes approximate calculations of the atmospheric transmittance, reflection, and solar scattering radiance for a finitely thin atmospheric layer. To verify its accuracy, the results for four typical scenarios(single molecular layer with Rayleigh scattering, single aerosol layer scattering, multi-layer Rayleigh scattering, and true atmospheric with multi-layer molecular absorption, Rayleigh and aerosol scattering) were compared with benchmarks from a well-known model. The comparison revealed an excellent agreement between the results and the reference data, with accuracy within a few thousandths. Besides, to fulfill the retrieval algorithm, a numerical differentiation-based Jacobian calculation method is developed for the atmospheric and surface parameters. This is coupled with the adding and doubling process for the radiative transfer calculation. The Jacobian matrix produced by the new algorithm is evaluated by comparison with that from the perturbation method. The relative Jacobian matrix deviations between the two methods are within a few thousandths for carbon dioxide and less than 1.0×10~(-3)% for aerosol optical depth. The two methods are consistent for surface albedo, with a deviation below 2.03×10~(-4)%. All validation results suggest that the accuracy of the proposed radiative transfer model is suitable for inversion applications. This model exhibits the potential for simulating near-infrared measurements of greenhouse gas monitoring instruments. 相似文献